We use repl.it as our primary environment during the first half of Intro to JavaScript classes for GirlDevelopIt (http://www.teaching-materials.org/javascript/)
It's a great way for students to try out JS in a fast way without worrying about the DOM. I also love that it's got JSHint built-in, as that helps students spot their errors faster.
I've used repl.it before many times, it's come in handy (especially at work) because our machines are locked down. Great way to experiment with implementing a particular req or just fooling around in general.
I would guess that the languages offered are those that can be converted to Javascript? If so are the others waiting to be added? Or is this the current offering?
I would imagine that other languages like C could be brought in if they could be compiled using emscripten. However, people have had problems bringing clang and llvm into emscripten: https://github.com/kripken/emscripten/issues/579
OCaml's repl is converted already to Javascript by using js_of_ocaml, so it should be possible to add it.
I just opened a feature request on jsREPL about this.